Rapid synthesis of arylgold compounds using dielectric heating.
نویسندگان
چکیده
Dielectric heating has been successfully used in the preparation of a range of arylgold compounds. The approach is tolerant of a number of functional groups and rapidly generates the organometallic complexes in moderate to excellent yields.
منابع مشابه
Acid, silver, and solvent-free gold-catalyzed hydrophenoxylation of internal alkynes
A range of arylgold compounds have been synthesized and investigated as single-component catalysts for the hydrophenoxylation of unactivated internal alkynes. Both carbene and phosphine-ligated compounds were screened as part of this work, and the most efficient catalysts contained either JohnPhos or IPr/SIPr. Phenols bearing either electron-withdrawing or electron-donating groups were efficien...
متن کاملSynthesis of Medicinally Privileged Heterocycles through Dielectric Heating.
BACKGROUND Heterocyclic compounds are intriguing part of modern drug discovery research. Ecofriendly syntheses of heterocycles, following green techniques, are privileged routes to protect Mother nature. Microwave-assisted synthesis of chemical compounds is considered as a major greener pathway, both in academia and industry. METHODS A total of 106 publications (including a few authentic web ...
متن کاملMicrowave plasma synthesis of lanthanide zirconates from microwave transparent oxides.
Lanthanide zirconate phases Ln(2)Zr(2)O(7) and Ln(4)Zr(3)O(12) (Ln = Y, La, Gd, Dy, Ho, Yb) have been prepared using a microwave induced plasma methodology, which allows rapid synthesis using materials which do not couple directly with microwaves at room temperature. We describe the measurement of heating profiles of the precursor binary metal oxides which can be used to identify conditions con...
متن کاملRapid and Green Synthesis of some Benzothiazole-, Benzimidazole- and Benzoxazole-2-thiol Derivatives Using Copper Sulfate in Aqueous Media
In this study an easy, green, efficient and simple approach is reported for the synthesis of some benzothiazole-, benzimidazole- and benzoxazole-2-thiolderivatives. The proposed approach employs the reaction of corresponding aromatic amine with potassium isopropyl xanthate (Z11) in the presence of copper sulfate (CuSO4) as a catalyst under conventional heating and ultrasonic irr...
متن کاملCuMn2O4 nanostructures: Facial synthesis, structural,magnetical, electrical characterization and activation energy calculation
The work is the report about stearic acid sol-gel synthesis method, magnetically, electricalcharacterization and activation energy of copper manganese oxide nanostructures. The CuMn2O4 nanostructures are synthesized at a temperature of 600°C using the sol-gel method. The structural analysis using X-ray diffraction (XRD) and Scherrer equation show that the crystallite size of CuMn2O4 is ab...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 41 43 شماره
صفحات -
تاریخ انتشار 2012